| Preferred name | cinnamon acrolein |
| Trivial Name | 3-(furan-2-yl)-2-methylprop-2-enal |
| Short Description | 2-methyl-3-(2-furyl)acrolein |
| Formula | C8 H8 O2 |
| CAS Number | 874-66-8 |
| CAS Number | 108576-21-2 |
| CAS Number | 874-66-8 (Z) |
| FEMA Number | 2704 |
| Flavis Number | 13.046 |
| ECHA Number | 212-866-9 |
| FDA UNII | 65U4YZ14MX |
| Nikkaji Number | J689.163B |
| COE Number | 11878 |
| NMR Predictor | External link |
| JECFA Food Flavoring | 1498 2-methyl-3-(2-furyl)acrolein |
| FDA Patent | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm | 874-66-8 ; 2-METHYL-3-(2-FURYL)ACROLEIN |
| Synonyms |
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| Google Scholar | Start search |
| Google Books | Start search |
| Google Patents | Start search |
| Perfumer & Flavorists | Start search |
| EU Patents | Start search |
| PubMeb | Start search |
| NCBI | Start search |
| 3-(furan-2-yl)-2-methylprop-2-enal | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 874-66-8 |
| Pubchem (cid): | 61228 |
| Pubchem (sid): | 43118514 |
| (E)-3-(furan-2-yl)-2-methylprop-2-enal | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 108576-21-2 |
| Pubchem (cid): | 6210220 |
| Pubchem (sid): | 42910720 |
| (Z)-3-furan-2-yl-2-methylprop-2-enal | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 874-66-8 |
| Pubchem (cid): | 6435828 |
| Pubchem (sid): | 197491 |
| Publications by Info | |
| substances containing furan substitution | |
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| HMDB (The Human Metabolome Database): | HMDB38176 |
| FooDB: | FDB017415 |
| Export Tariff Code: | 2932.19.0090 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
| EFSA Update of results on the monitoring of furan levels in food: | Read Report |
| EFSA Previous report: Results on the monitoring of furan levels in food: | Read Report |
| EFSA Report of the CONTAM Panel on provisional findings on furan in food: | Read Report |
| Material listed in food chemical codex | No |
| Molecular weight | 136.15016174316 |
| Specific gravity | @ 25 °C |
| Pounds per Gallon | 9.053 to 9.145 |
| Refractive Index | 1.48 to 1.61 @ 20 °C |
| Acid Value | 3 max KOH/g |
| Vapor Pressure | 0.113 mmHg @ 25 °C |
| Vapor Density | 4.6 |
| Flash Point TCC Value | 101.67 °C TCC |
| logP (o/w) | 1.741 est |
| Solubility | |
| alcohol | Yes |
| water, 2865 mg/L @ 25 °C (est) | Yes |
| water | No |
| Odor Type: Spicy | |
| spicy, cinnamon, woody, herbal, cassia, medicinal | |
| General comment | At 10.00 % in dipropylene glycol. spice cinnamon woody herbal |
| Mosciano, Gerard P&F 22, No. 2, 69, (1997) | Spicy, cassia, cinnamon and woody with herbal, medicinal nuances |
| Flavor Type: Spicy | |
| spicy, cinnamon, cassia, woody | |
| Mosciano, Gerard P&F 22, No. 2, 69, (1997) | At 10.00 ppm. Spicy, cinnamon, cassia and woody with a red-hot candy naunce |
| Used in cinnamon and spice flavors. | Spicy |
| Used in spicy, fruit and nut flavours, for bakery at 15ppm, non-alcoholic beverages at 4ppm, confectionery and desserts 3ppm, and alcoholic beverages at 1ppm. | Spicy |
| (data available) |
| Applications | |
| Odor purposes | Blackberry , Cassia , Cinnamon , Clove , Coffee , Herbal , Mace , Peanut , Raspberry , Spice , Woody |
| Flavoring purposes | Cola , Fruit tropical fruit , Nut |
| European information : | |
| Most important hazard(s): | |
| Xn - Harmful. | |
| R 22 - Harmful if swallowed. R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| oral-rat LD50 1400 mg/kg SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE SKIN AND APPENDAGES (SKIN): HAIR: OTHER GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 3, 1990. | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
| Category: | |||
| flavor and fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for cinnamon acrolein usage levels up to: | |||
| 0.5000 % in the fragrance concentrate. | |||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.24 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 6.00 (μg/capita/day) | ||
| Structure Class: | III | ||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 3 | |||
| Click here to view publication 3 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | - | 0.92000 | |
| beverages(nonalcoholic): | - | 0.60000 | |
| beverages(alcoholic): | - | - | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | - | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 0.65000 | |
| fruit ices: | - | 0.65000 | |
| gelatins / puddings: | - | - | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | - | 0.68000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
| European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
| Flavouring Group Evaluation 67 (FGE.67): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf |
| Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf |
| Scientific Opinion on Flavouring Group Evaluation 222 (FGE.222): Consideration of genotoxicity data on representatives for alpha,beta-unsaturated furyl derivatives with the a,ß-unsaturation in the side chain from subgroup 4.6 of FGE.19 by EFSA View page or View pdf |
| Scientific Opinion on Flavouring Group Evaluation 67, Revision 3 (FGE.67Rev3): consideration of 23 furan-substituted compounds evaluated by JECFA at the 55th, 65th, 69th and 86th meetings View page or View pdf |
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):874-66-8 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :61228 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:3 |
| 3-(furan-2-yl)-2-methylprop-2-enal |
| Chemidplus:0000874668 |
| (E)-3-(furan-2-yl)-2-methylprop-2-enal |
| (Z)-3-furan-2-yl-2-methylprop-2-enal |